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Corrosion Inhibition Screening of 2-((6-aminopyridin-2-yl)imino)indolin-3-one: Weight Loss, Morphology, and DFT Investigations

  • Nadia Betti (Materials Engineering Department, University of Technology-Iraq) ;
  • Ahmed A. Al-Amiery (Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia (UKM))
  • Received : 2022.07.12
  • Accepted : 2022.10.26
  • Published : 2023.03.02

Abstract

Because of its inexpensive cost, mild steel is frequently employed as a construction material in different industries. Unfortunately, because of its limited resistance to corrosion, a protective layer must be applied to keep it from decaying in acidic or basic environments. The presence of heteroatoms, such as nitrogen, oxygen, and pi-electrons in the Schiff base could cause effective adsorption on the mild steel surface, preventing corrosion. The weight loss method and scanning electron microscopy (SEM) were used to investigate the inhibitory effects of APIDO on mild steel in a 1 M hydrochloric acid environment. The efficiency of inhibition increased as the inhibitor concentration increased and decreased as the temperature increased. The SEM analysis confirmed that the corrosion inhibition of APIDO proceeded by the formation of an organic protective layer over the mild steel surface by the adsorption process. Simulations based on the density functional theory are used to associate inhibitory efficacy with basic molecular characteristics. The findings acquired were compatible with the experimental information provided in the research.

Keywords

References

  1. T. A. Salman, A. A. Al-Amiery, L. M. Shaker, A. A. Kadhum, M. S. Takriff, A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl) thiazole-5-carbohydrazide, The International Journal of Corrosion and Scale Inhibition, 8, 1035 (2019). Doi: https://doi.org/10.17675/2305-6894-2019-8-4-14
  2. H. J. Habeeb, H. M. Luaibi, T. A. Abdullah, R. M. Dakhil, R. M. Kadhum, A. A. Al-Amiery, Case study on thermal impact of novel corrosion inhibitor on mild steel, Case Studies in Thermal Engineering, 12, 64 (2018). Doi: https://doi.org/10.1016/j.csite.2018.03.005
  3. T. A. Salman, Q. A. Jawad, M. A. Hussain, A. A. AlAmiery, L. Mohamed, A. A. Kadhum, M. S. Takriff, Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects, The International Journal of Corrosion and Scale Inhibition, 8, 1123 (2019). Doi: https://doi.org/10.17675/2305-6894-2019-8-4-19
  4. A. A. Alamiery, W. N. Wan Isahak, M. S. Takriff, Inhibition of Mild Steel Corrosion by 4-benzyl-1-(4-oxo-4-phenylbutanoyl) thiosemicarbazide: Gravimetrical, Adsorption and Theoretical Studies, Lubricants, 9, 93 (2021). Doi: https://doi.org/10.3390/lubricants9090093
  5. D. M. Jamil, A. K. Al-Okbi, M. M. Hanon, K. S. Rida, A. F. Alkaim, A. A. Al-Amiery, A. Kadhim, A. A. Kadhum, Carbethoxythiazole corrosion inhibitor: As an experimentally model and DFT theory, Jounal of Engineering and Applied Science, 13, 3952 (2018). Doi: https://doi.org/10.36478/jeasci.2018.3952.3959
  6. A. Y. Musa, W. Ahmoda, A. A. Al-Amiery, A. A. Kadhum, A. B. Mohamad, Quantum chemical calculation for the inhibitory effect of compounds, Journal of Structural Chemistry, 54, 301 (2013). Doi: https://doi.org/10.1134/S0022476613020042
  7. S. Al-Baghdadi, T. S. Gaaz, A. Al-Adili, A. A. AlAmiery, M. S. Takriff, Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation, International Journal Low-Carbon Technology, 16, 181 (2021). Doi: https://doi.org/10.1093/ijlct/ctaa050
  8. A. Al-Amiery, T. A. Salman, K. F. Alazawi, L. M. Shaker, A. A. Kadhum, M. S. Takriff, Quantum chemical elucidation on corrosion inhibition efficiency of Schiff base: DFT investigations supported by weight loss and SEM techniques, International Journal Low-Carbon Technology, 15, 202 (2020). Doi: https://doi.org/10.1093/ijlct/ctz074
  9. T. A. Salman, K. F. Al-Azawi, I. M. Mohammed, S. B. Al-Baghdadi, A. A. Al-Amiery, T. S. Gaaz, A. A. Kadhum, Experimental studies on inhibition of mild steel corrosion by novel synthesized inhibitor complemented with quantum chemical calculations, Results in Physics, 10, 291 (2018). Doi: https://doi.org/10.1016/j.rinp.2018.06.019
  10. D. S. Zinad, M. Hanoon, R. D. Salim, S. I. Ibrahim, A. A. Al-Amiery, M. S. Takriff, A. A. Kadhum, A new synthesized coumarin-derived Schiff base as a corrosion inhibitor of mild steel surface in HCl medium: Gravimetric and DFT studies, The International Journal of Corrosion and Scale Inhibition, 9, 228 (2020). Doi: https://doi.org/10.17675/2305-6894-2020-9-1-14
  11. A. A. Alamiery, Effect of Temperature on the Corrosion Inhibition of 4-ethyl-1-(4-oxo-4-phenylbutanoyl)thiosemicarbazide on Mild Steel in HCl Solution, Letters in Applied NanoBioScience, 11, 3502 (2022). Doi: https://doi.org/10.33263/LIANBS112.35023508
  12. ASTM G1, Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test, pp. 1 - 9, ASTM International (2011). Doi: http://dx.doi.org/10.1520/G0001-03R11
  13. D. S. Zinad, Q. A. Jawad, M. A. Hussain, A. Mahal, L. Mohamed, A. A. Al-Amiery, Adsorption, temperature and corrosion inhibition studies of a coumarin derivatives corrosion inhibitor for mild steel in acidic medium: Gravimetric and theoretical investigations, International Journal of Corrosion and Scale Inhibition, 9, 134 (2020). Doi: https://doi.org/10.17675/2305-6894-2020-9-1-8
  14. J. A. Yamin, E. A. Sheet, A. Al-Amiery, Statistical analysis and optimization of the corrosion inhibition efficiency of a locally made corrosion inhibitor under different operating variables using RSM, International Journal of Corrosion and Scale Inhibiton, 9, 502 (2020). Doi: http://doi.org/10.17675/2305-6894-2020-9-2-6
  15. T. A. Salman, D. S. Zinad, S. H. Jaber, M. Al-Ghezi, A. Mahal, M. S. Takriff, A. A. Al-Amiery, Effect of 1, 3, 4-thiadiazole scaffold on the corrosion inhibition of mild steel in acidic medium: An experimental and computational study, Journal Bio-and Tribo-Corrosion, 5, 11 (2019). Doi: https://doi.org/10.1007/s40735-019-0243-7
  16. T. Koopmans Ordering of wave functions and eigenenergies to the individual electrons of an atom. Physica, 1, 104 (1933). Doi: https://doi.org/10.1016/S0031-8914(34)90011-2
  17. S. B. Al-Baghdadi, A. A. Al-Amiery, A. A. Kadhum, M. S. Takriff, Computational Calculations, Gravimetrical, and Surface Morphological Investigations of Corrosion Inhibition Effect of Triazole Derivative on Mild Steel in HCl, Journal of Computational and Theoretical Nanoscience, 17, 2897 (2020). Doi: https://doi.org/10.1166/jctn.2020.9328
  18. M. M. Hanoon, Z. A. Gbashi, A. A. Al-Amiery, A. Kadhim, A. A. Kadhum, M. S. Takriff, Study of Corrosion Behavior of N'-acetyl-4-pyrrol-1-ylbenzohydrazide for Low-Carbon Steel in the Acid Environment: Experimental, Adsorption Mechanism, Surface Investigation, and DFT Studies, Progress in Color Colorants and Coatings, 15, 133 (2022). Doi: https://dx.doi.org/10.30509/PCCC.2021.166836.1118
  19. M. M. Hanoon, A. M. Resen, A. A. Al-Amiery, A. A. Kadhum, M. S. Takriff, Theoretical and Experimental Studies on the Corrosion Inhibition Potentials of 2-((6- Methyl-2-Ketoquinolin-3-yl) Methylene) Hydrazinecarbothioamide for Mild Steel in 1 M HCl, Progress in Color Colorants and Coatings, 15, 11 (2022). Doi: https://dx.doi.org/10.30509/PCCC.2020.166739.1095
  20. A. A. Al-Amiery, W. K. Al-Azzawi, W. N. R. W. Isahak, Isatin Schiff base is an effective corrosion inhibitor for mild steel in hydrochloric acid solution: gravimetrical, electrochemical, and computational investigation, Scientific Reports, 12, 17773 (2022). Doi: https://doi.org/10.1038/s41598-022-22611-4
  21. N. Betti, A. A. Al-Amiery, W. K. Al-Azzawi, Experimental and Quantum Chemical Investigations on the Anticorrosion Efficiency of a Nicotinehydrazide Derivative for Mild Steel in HCl, Molecules, 27, 6254 (2022). Doi: https://doi.org/10.3390/molecules27196254
  22. B. S. Mahdi, M. K. Abbass, M. K. Mohsin, W. K. Alazzawi, M. M. Hanoon, M. H. H. Al-kaabi, L. M. Shaker, A. A. Al-amiery, W. N. R. W. Isahak, A. A. H. Kadhum, M. S. Takriff, Corrosion Inhibition of Mild Steel in Hydrochloric Acid Environment Using Terephthaldehyde Based on Schiff Base: Gravimetric, Thermodynamic, and Computational Studies, Molecules, 27, 4857 (2022). Doi: https://doi.org/10.3390/molecules27154857
  23. I. A. A. Aziz, M. H. Abdulkareem, I. A. Annon, M. M. Hanoon, M. H. H. Al-Kaabi, L. M. Shaker, A. A. Alamiery, W. N. R. W. Isahak, M. S. Takriff, Weight Loss, Thermodynamics, SEM, and Electrochemical Studies on N-2-Methylbenzylidene-4-antipyrineamine as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid, Lubricants, 10, 23 (2022). Doi: https://doi.org/10.3390/lubricants10020023
  24. I. A. Alkadir Aziz, I. A. Annon, M. H. Abdulkareem, M. M.Hanoon, M. H. Alkaabi, L. M. Shaker, A. A. Alamiery, W. N. R. Wan Isahak, M. S. Takriff, Insights into Corrosion Inhibition Behavior of a 5-Mercapto-1, 2, 4-triazole Derivative for Mild Steel in Hydrochloric Acid Solution: Experimental and DFT Studies, Lubricants, 9, 122 (2021). Doi: https://doi.org/10.3390/lubricants9120122
  25. A. A. Alamiery, W. N. R. Wan Isahak, M. S. Takriff, Inhibition of Mild Steel Corrosion by 4-benzyl-1-(4-oxo-4-phenylbutanoyl)thiosemicarbazide: Gravimetrical, Adsorption and Theoretical Studies, Lubricants, 9, 93 (2021). Doi: https://doi.org/10.3390/lubricants9090093
  26. A. Alamiery, Corrosion inhibition effect of 2-N-phenylamino-5-(3-phenyl-3-oxo-1-propyl)-1, 3, 4-oxadiazole on mild steel in 1 M hydrochloric acid medium: Insight from gravimetric and DFT investigations, Materials Science for Energy Technologies, 4, 398 (2021). Doi: https://doi.org/10.1016/j.mset.2021.09.002
  27. A. A. Alamiery, Anticorrosion effect of thiosemicarbazide derivative on mild steel in 1 M hydrochloric acid and 0.5 M sulfuric Acid: Gravimetrical and theoretical studies. Materials Science for Energy Technologies, 4, 263 (2021). Doi: https://doi.org/10.1016/j.mset.2021.07.004
  28. I. Aziz, I. Annon, M. H. Abdulkareem, M. M. Hanoon, M. H. Alkaabi, L. M. Shaker, A. A. Alamiery, W. N. R. Wan Isahak, and M. S. Takriff, Insights into Corrosion Inhibition Behavior of a 5-Mercapto-1, 2, 4-triazole Derivative for Mild Steel in Hydrochloric Acid Solution: Experimental and DFT Studies, Lubricants, 9, 122 (2021). Doi: https://doi.org/10.3390/lubricants9120122
  29. A. Nahle, R. Salim, F. El Hajjaji, M. R. Aouad, M. Messali, E. Ech-Chihbi, B. Hammouti, M. Taleb, Novel triazole derivatives as ecological corrosion inhibitors for mild steel in 1.0 M HCl: Experimental & theoretical approach, RSC Advances, 11, 4147 (2021). Doi: https://doi.org/10.1039/D0RA09679B
  30. A. Espinoza-Vazquez, F. J. Rodriguez-Gomez, I. K. Martinez-Cruz, D. Angeles-Beltran, G. E. Negron-Silva, M. Palomar-Pardave, L. L. Romero, D. Perez-Martinez, A. M. Navarrete-Lopez, Adsorption and corrosion inhibition behaviour of new theophylline-triazole-based derivatives for steel in acidic medium, Royal Society Open Science, 6, 181738 (2019). Doi: https://doi.org/10.1098/rsos.181738
  31. I. Merimi, R. Benkaddour, H. Lgaz, N. Rezki, M. Messali, F. Jeffali, H. Oudda, B. Hammouti, Insights into corrosion inhibition behavior of a triazole derivative for mild steel in hydrochloric acid solution, Materials Today Proceedings, 13, 1008 (2019). Doi: https://doi.org/10.1016/j.matpr.2019.04.066
  32. L. Wang, M. J. Zhu, F. C. Yang, C. W. Gao, Study of a triazole derivative as corrosion inhibitor for mild steel in phosphoric acid solution, International Journal of Corrosion, 2012, 573964 (2012). Doi: https://doi.org/10.1155/2012/573964
  33. F. Bentiss, M. Bouanis, B. Mernari, M. Traisnel, H. Vezin, M. Lagrenee, Understanding the adsorption of 4H1, 2, 4-triazole derivatives on mild steel surface in molar hydrochloric acid, Applied Surface Science, 253, 3696 (2007). Doi: https://doi.org/10.1016/j.apsusc.2006.08.001
  34. B. El Mehdi, B. Mernari, M. Traisnel, F. Bentiss, M. Lagrenee, Synthesis and comparative study of the inhibitive effect of some new triazole derivatives towards corrosion of mild steel in hydrochloric acid solution, Materials Chemistry and Physics, 77, 489 (2003). Doi: https://doi.org/10.1016/S0254-0584(02)00085-8
  35. H. H Hassan, E. Abdelghani, M. A. Amin, Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives: Part I. Polariztion and EIS Studies, Electrochimica Acta, 52, 6359 (2007). Doi: https://doi.org/10.1016/j.electacta.2007.04.046
  36. S. Ramesh, S. Rajeswari, Corrosion inhibition of mild steel in neutral aqueous solution by new triazole derivatives, Electrochimica Acta, 49, 811 (2004). Doi: https://doi.org/10.1016/j.electacta.2003.09.035